Computational Mechanisms of Au and Pt Catalyzed Reactions
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- 239,99 €
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- 239,99 €
Description de l’éditeur
See Table of Contents (PMP) Complexes of Pt and Au (gold(III) and cationic gold(I)) have shown an exceptional ability to promote a variety of organic transformations of unsaturated precursors due to their peculiar Lewis acid properties: the alkynophilic character of these soft metals and the p-acid activation of unsaturated groups promotes the intra- or intermolecular attack of a nucleophile. In this chapter we summarize the computational data reported on the structure, bonding, and reactivity of the reactant p-complexes and also on the key intermediate species