Catalysis In Micellar and Macromolecular Systems

Catalysis in Micellar and Macromolecular Systems provides a comprehensive monograph on the catalyses elicited by aqueous and nonaqueous micelles, synthetic and naturally occurring polymers, and phase-transfer catalysts. It delineates the principles involved in designing appropriate catalytic systems throughout. Additionally, an attempt has been made to tabulate the available data exhaustively. The book discusses the preparation and purification of surfactants; the physical and chemical properties of surfactants and micelles; solubilization in aqueous micellar systems; and the principles of micellar catalysis. Separate chapters cover micellar catalysis of hydrolyses, solvolyses, aminolyses, and miscellaneous ionic reactions; micellar effects on organic equilibria and nucleophilic substitution reactions, and on hydrophobic interactions and protein structure; and radical and excited state reactions in micellar systems.