Heterocycle Synthesis Via Radical Reactions * (Report) Heterocycle Synthesis Via Radical Reactions * (Report)

Heterocycle Synthesis Via Radical Reactions * (Report‪)‬

Pure and Applied Chemistry 2008, April, 80, 4

Pure and Applied Chemistry
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Publisher Description

Abstract: A novel synthetic method for the preparation of nitrogen-containing heterocycles via the route involving domino-type radical addition/cyclization reaction of oxime ethers is described. Alkyl radical addition/cyclization of oxime ethers carrying an appropriate leaving group proceeded smoothly to form the alkylated nitrogen-containing heterocyclic compounds. Additionally, tin-mediated radical addition/cyclization/elimination (RACE) reaction of oxime ethers is newly found and successfully applied to an asymmetric total synthesis of (--)-martinellic acid. Keywords: radical reaction; oxime ethers; domino reaction: bgugaine; martinellic acid.

GENRE
Science & Nature
RELEASED
2008
April 1
LANGUAGE
EN
English
LENGTH
12
Pages
PUBLISHER
International Union of Pure and Applied Chemistry
SELLER
The Gale Group, Inc., a Delaware corporation and an affiliate of Cengage Learning, Inc.
SIZE
171.8
KB

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